Volume 31, Issue 23
Isocyclic Compounds
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ChemInform Abstract: A New and Efficient Synthesis of ortho- and para-Benzoquinones of Cardanol Derivatives by the Catalytic System MeReO3—H2O2.

Raffaele Saladino

Raffaele Saladino

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Veronica Neri

Veronica Neri

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Enrico Mincione

Enrico Mincione

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Stefano Marini

Stefano Marini

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Massimiliano Coletta

Massimiliano Coletta

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Chiara Fiorucci

Chiara Fiorucci

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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Paolino Filippone

Paolino Filippone

Dip. Agrochim. Agrobiol., Univ. Stud. “La Tuscia”, I-01100 Viterbo, Italy

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First published: 08 June 2010

Abstract

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ChemInform Abstract

Cardanol, the main component of roasted cashew nut shell liquid, is a mixture of 3-pentadecylphenol and related derivatives with partially unsaturated sidechain which can be used as stabilizers for various organic compounds including foods. The first catalytic preparation of cardanol-derived o- and p-benzoquinones using the H2O2/MeReO3 system is presented. In addition to the starting materials compounds (II) and (VI) show potent cytotoxic activity against murine fibroblast cell line.

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