ChemInform Abstract: Reactivity of Primary and Secondary Alcohols in Nucleophilic Addition to a Triple Bond: The Vinylation of Butane-1,3-diol.
Abstract
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ChemInform Abstract
KOH-catalyzed addition of acetylene to butane-1,3-diol (I) affords vinyl ethers (III), (IV), (VI) and dioxane (V) in ratios depending on the reaction conditions.