ChemInform Abstract: [Mn(en)3]CdSnTe4 and [Mn(en)3]Ag6Sn2Te8: New Intermetallic Tellurides Synthesized in Superheated Organic Medium.
Abstract
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ChemInform Abstract
Title compound (V) crystallizes in the triclinic space group P1 with Z = 2 and (VII) in the trigonal space group R
m with Z = 3 (single crystal XRD). Both compounds possess new structure types. The structure of (V) is composed of one-dimensional Zintl chains of alternating edge-sharing CdTe4 and MnTe4 tetrahedra with the complex [Mn(en)3]2+ cations located between the chains. The structure of (VII) contains [Ag6Sn2Te82-] double-layers formed by two honeycomb-like layers which are connected via M—Te bonds (M: Ag, Sn). The double layers are separated by the [Mn(en)3]2+ templates. Both compounds are semiconductors.
