Volume 31, Issue 12
Natural Products
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ChemInform Abstract: Novel Synthesis and Structures of Amines and Triazole-Derived Glycoside and Nucleoside Derivatives of Phosphanyl Sugar Analogues.

Mitsuji Yamashita

Mitsuji Yamashita

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Kazumitsu Suzuki

Kazumitsu Suzuki

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Yukihiro Kato

Yukihiro Kato

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Akihito Iida

Akihito Iida

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Koichi Ikai

Koichi Ikai

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Putta Mallikarjuna Reddy

Putta Mallikarjuna Reddy

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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Tatsuo Oshikawa

Tatsuo Oshikawa

Dep. Mater. Chem., Fac. Eng., Shizuoka Univ., Hamamatsu, Shizuoka 432, Japan

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Novel glycoside derivatives of phosphanyl sugar analogues such as (III) and (V) are synthesized with retention of configuration using the appropriate 2-phospholenes as starting materials. Reaction of azide (V) with alkynes gives compounds (VII), (IX), (XI), and (XII) as novel triazole-derived nucleosides.

chemical structure image

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