Volume 31, Issue 12
Organoelement Compounds
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ChemInform Abstract: A Practical Method for the Large-Scale Synthesis of Diastereomerically Pure (2R,5S)-3-Phenyl-2-(8-quinolinoxy)-1,3-diaza-2-phosphabicyclo- [3.3.0]-octane Ligand (QUIPHOS). Synthesis and X-Ray Structure of Its Corresponding Chiral π-Allyl Palladium Complex.

Jean Michel Brunel

Jean Michel Brunel

Ec. Natl. Super. Synth., Procedes Ing. Chim., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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Thierry Constantieux

Thierry Constantieux

Ec. Natl. Super. Synth., Procedes Ing. Chim., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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Gerard Buono

Gerard Buono

Ec. Natl. Super. Synth., Procedes Ing. Chim., CNRS, Fac. Sci. St. Jerome, Univ. Aix-Marseille III, F-13397 Marseille, Fr.

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First published: 09 June 2010

Abstract

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ChemInform Abstract

The title compound (QUIPHOS) is an efficient ligand in asymmetric allylations.

chemical structure image

    The full text of this article hosted at iucr.org is unavailable due to technical difficulties.