Volume 31, Issue 12
Organoelement Compounds
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ChemInform Abstract: Stereoselective Addition of Sodium Organyl Chalcogenolates to Alkynylphosphonates: Synthesis of Diethyl 2-(Organyl)-2-(organochalcogenyl)vinylphosphonates.

Antonio L. Braga

Antonio L. Braga

Dep. Quim., Univ. Fed. Santa Maria, 97119 Santa Maria, Rio Grande do Sul, Brazil

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Elenilson F. Alves

Elenilson F. Alves

Dep. Quim., Univ. Fed. Santa Maria, 97119 Santa Maria, Rio Grande do Sul, Brazil

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Claudio C. Silveira

Claudio C. Silveira

Dep. Quim., Univ. Fed. Santa Maria, 97119 Santa Maria, Rio Grande do Sul, Brazil

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Leandro H. de Andrade

Leandro H. de Andrade

Dep. Quim., Univ. Fed. Santa Maria, 97119 Santa Maria, Rio Grande do Sul, Brazil

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First published: 09 June 2010

Abstract

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ChemInform Abstract

Organyl chalcogenolates undergo stereoselective addition to alkynylphosphonates (II) providing mainly or exclusively the Z-adducts.

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