ChemInform Abstract: Synthesis of Difunctional 1,4-Dimethyl-1,4-disilacyclohexanes.
Abstract
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ChemInform Abstract
Pt-catalyzed homohydrosilylation of vinyl(hydrogen)silanes affords mixtures of five- and six-membered disilacyclanes resulting from intramolecular cyclization of initially formed linear dimers. In the case of methyl(phenyl)disilacyclane, the structural and stereoisomers can be separated. Some structural transformations of pure trans-disilacyclohexane (IV) [→(V), (VI)] are described.
