Volume 31, Issue 12
Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of Allylic and Propargylic Primary Amines by Reaction of Organometallic Reagents with α-Amidoalkyl Sulfones.

Tiziana Mecozzi

Tiziana Mecozzi

Dip. Sci. Chim., Univ. Camerino, I-62032 Camerino, Macerata, Italy

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Marino Petrini

Marino Petrini

Dip. Sci. Chim., Univ. Camerino, I-62032 Camerino, Macerata, Italy

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First published: 09 June 2010

Abstract

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ChemInform Abstract

α-Amidoalkyl sulfones are found to be useful synthetic equivalents of N-acyl imines. Their reaction with organometallic reagents gives N-protected primary amines like (VI) and (VIII) in good yields.

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