Volume 31, Issue 12
Preparative Organic Chemistry
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ChemInform Abstract: Catalytic Conjugate Addition Promoted by the Copper(I) Monothiobinaphthol System. Part 3. Comparison of Three Thiolate-Based Catalytic Systems.

Simon M. W. Bennett

Simon M. W. Bennett

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Stephen M. Brown

Stephen M. Brown

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Grainne Conole

Grainne Conole

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Michael R. Dennis

Michael R. Dennis

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Paul K. Fraser

Paul K. Fraser

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Sanja Radojevic

Sanja Radojevic

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Mary McPartlin

Mary McPartlin

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Chris M. Topping

Chris M. Topping

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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Simon Woodward

Simon Woodward

Dep. Chem., Univ. Hull, Kingston-upon-Hull HU6 7RX, UK

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First published: 09 June 2010

Abstract

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ChemInform Abstract

High chemoselectivity and low but significant enantioselectivity is observed in the title reaction. Ligand (Ib) is prepared by an anionic Fries-rearrangement (configuration of (VII) not assigned, only GC yields given).

chemical structure image

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