ChemInform Abstract: Catalytic Conjugate Addition Promoted by the Copper(I) Monothiobinaphthol System. Part 3. Comparison of Three Thiolate-Based Catalytic Systems.
Abstract
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ChemInform Abstract
High chemoselectivity and low but significant enantioselectivity is observed in the title reaction. Ligand (Ib) is prepared by an anionic Fries-rearrangement (configuration of (VII) not assigned, only GC yields given).