ChemInform Abstract: Electrodeposited Quantum Dots: Metastable Rocksalt CdSe Nanocrystals on [111] Gold Alloys.
Abstract
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ChemInform Abstract
The initial growth of CdSe, electrodeposited from a DMSO solution containing elemental Se and Cd(ClO4)2 onto a Cd-Au substrate, is in the form of thin (1.5 nm) epitaxial octahedral rocksalt-type nanocrystals. As the crystals grow thicker, a phase transition to a CdSe mixture with wurtzite and sphalerite type structure occurs.