Volume 31, Issue 7
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ChemInform Abstract: Formation of Hollow Helicoids in Mesoporous Silica: Supramolecular Origami.

San Ming Yang

San Ming Yang

Mater. Chem. Res. Group, Lash Miller Chem. Lab., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.

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Igor Sokolov

Igor Sokolov

Mater. Chem. Res. Group, Lash Miller Chem. Lab., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.

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Neil Coombs

Neil Coombs

Mater. Chem. Res. Group, Lash Miller Chem. Lab., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.

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Charles T. Kresge

Charles T. Kresge

Mater. Chem. Res. Group, Lash Miller Chem. Lab., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.

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Geoffrey A. Ozin

Geoffrey A. Ozin

Mater. Chem. Res. Group, Lash Miller Chem. Lab., Univ. Toronto, Toronto, Ont. M5S 3H6, Can.

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First published: 10 June 2010

Abstract

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ChemInform Abstract

Novel hollow helicoid morphologies made up of hexagonal mesoporous silica are prepared using cetyltrimethylammonium chloride as surfactant micellar template and Si(OEt)4 as Si source. The hollow helicoids have the shape of an “Archimedian screw”. Siliceous hollow helicoids with spiraling mesoscale channels may find application in separating viral or bacterial particles, in chiral catalysis of macromolecules, or in the fabrication of magnetically activated screws for micro-devices.

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