Volume 31, Issue 7
Heterocyclic Compounds
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ChemInform Abstract: Enantio-Differentiating Hydrogenation of Methyl 2-Furoylacetate and Its Analogues over Tartaric Acid-Modified Raney Nickel.

Satoshi Nakagawa

Satoshi Nakagawa

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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Noriko Haruna

Noriko Haruna

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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Delicia E. Acosta

Delicia E. Acosta

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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Tadateru Endo

Tadateru Endo

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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Takashi Sugimura

Takashi Sugimura

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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Akira Tai

Akira Tai

Fac. Sci., Himeji Inst. Technol., Kamigori, Hyogo 678-12, Japan

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First published: 10 June 2010

Abstract

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ChemInform Abstract

Hydrogenation of the β-ketoester (I) and its analogues, e.g. (IV), containing a furan moiety besides the reaction site, gives good enantio-differentiation at the 3-position.

chemical structure image

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