Volume 31, Issue 7
Isocyclic Compounds
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ChemInform Abstract: Induced Oxidative Rearrangement of Nonterminal Alkynes by [Fluoro(trifluoromethanesulfonyloxy)iodo]benzene to Esters of 2-Alkyl- and 2-Arylalkanoic Acids.

Namig Sh. Pirguliyev

Namig Sh. Pirguliyev

Inst. Physiol. Act. Compd., Russ. Acad. Sci., Moscow 142432, Russia

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Valery K. Brel

Valery K. Brel

Inst. Physiol. Act. Compd., Russ. Acad. Sci., Moscow 142432, Russia

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Nikolai S. Zefirov

Nikolai S. Zefirov

Inst. Physiol. Act. Compd., Russ. Acad. Sci., Moscow 142432, Russia

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Peter J. Stang

Peter J. Stang

Inst. Physiol. Act. Compd., Russ. Acad. Sci., Moscow 142432, Russia

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First published: 10 June 2010

Abstract

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ChemInform Abstract

The iodine(III)-induced oxidative rearrangement of non-terminal acetylenes by the title reagent offers an efficient procedure for the specific transformation of alkynes to alkyl- and arylalkanoic acids.

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