Volume 31, Issue 7
Preparative Organic Chemistry
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ChemInform Abstract: Electroinduced Oxidative Transformation of 2,5-Dioxabicyclo[4.4.0]decanes into 5-(1,3-Dioxolan-2-yl)- and 5-(Dimethoxymethyl)pentanoates.

Yuri N. Ogibin

Yuri N. Ogibin

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Alexander O. Terent'ev

Alexander O. Terent'ev

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Alexey I. Ilovaisky

Alexey I. Ilovaisky

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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Gennady I. Nikishin

Gennady I. Nikishin

Zelinsky Inst. Org. Chem., Russ. Acad. Sci., Moscow 117913, Russia

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First published: 10 June 2010

Abstract

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ChemInform Abstract

The electrooxidative transformation of some dioxabicyclodecanes into pentanoate (III) or dioxolane (VI), is described. However, this rearrangement is not a general case, and it is typical of only a limited range of compounds of this kind.

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