ChemInform Abstract: Diastereoselectivity in the Reduction of Acyclic Carbonyl Compounds with Diisopropoxytitanium(III) Tetrahydroborate.
Abstract
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ChemInform Abstract
The reduction of carbonyl compounds using Ti(O-iPr)2BH4 is proposed to proceed via an intramolecular hydride transfer based on comparison of the stereoselectivities obtained by the present method with reported data obtained using other methods.