Volume 30, Issue 52
Preparative Organic Chemistry
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ChemInform Abstract: Diastereoselectivity in the Reduction of Acyclic Carbonyl Compounds with Diisopropoxytitanium(III) Tetrahydroborate.

K. S. Ravikumar

K. S. Ravikumar

Dep. Org. Chem., Indian Inst. Sci., Bangalore 560 012, India

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Surajit Sinha

Surajit Sinha

Dep. Org. Chem., Indian Inst. Sci., Bangalore 560 012, India

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S. Chandrasekaran

S. Chandrasekaran

Dep. Org. Chem., Indian Inst. Sci., Bangalore 560 012, India

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First published: 12 June 2010

Abstract

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ChemInform Abstract

The reduction of carbonyl compounds using Ti(O-iPr)2BH4 is proposed to proceed via an intramolecular hydride transfer based on comparison of the stereoselectivities obtained by the present method with reported data obtained using other methods.

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