Volume 30, Issue 29
Isocyclic Compounds
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ChemInform Abstract: Enantioselective Synthesis of Cyclopentane Derivatives Using Zirconium-Catalyzed Asymmetric Cyclization.

Yousuke Yamaura

Yousuke Yamaura

Grad. Sch. Pharm. Sci., Hokkaido Univ., Sapporo 060, Japan

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Miwako Mori

Miwako Mori

Grad. Sch. Pharm. Sci., Hokkaido Univ., Sapporo 060, Japan

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First published: 14 June 2010

Abstract

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ChemInform Abstract

The cyclization of dienes such as (I), (IV), and (VI) in the presence of Bu-MgCl and a chiral Zr-catalyst is studied. Optically active highly substituted cyclopentanes are obtained in good to high enantioselectivities.

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