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ChemInform Abstract: Stereocontrolled Synthesis of the Fully Elaborated Aziridine Core of the Azinomycins.
First published: 20 June 2010
Abstract
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ChemInform Abstract
The aziridino[1,2-a]pyrrolidine substructure of the antitumor agents Azinomycin A and B, isolated from Streptomyces griseofuscus, is synthesized from the key aldehyde (IV), which is obtained from (I) in 8 steps and 35% yield.
