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ChemInform Abstract: Studies on the Chemoselectivity and Diastereoselectivity of Samarium(II) Iodide Mediated Transformations of Carbohydrate-Derived ω-Halo-α,β-Unsaturated Esters.
First published: 20 June 2010
Abstract
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ChemInform Abstract
The chemoselectivity and diastereoselectivity of SmI2 reductions of D-ribonolactone-derived ω-iodo- and ω-bromo-α,β-unsaturated esters is affected by the solvent system, the identity of the halide, the double bond geometry, and the type of the ester used.
