ChemInform Abstract: Total Synthesis of (+)-3-Oxacarbacyclin. Part 2. Stereoselective Deprotonation and Completion of the Synthesis.
Abstract
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ChemInform Abstract
The key steps in the synthesis of the title compound (X) are diastereoselective formation of the ester (I) described in the preceding paper, stereoselective deprotonation of the ketone (III) and stereoselective reduction of the keto group in compound (IX). This method can also be applied to prepare cicaprost, eptaloprost, and other side-chain modified 3-oxacarbacyclins.
