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ChemInform Abstract: Stereochemistry of the Methyl→Methylene Elimination in the Enzyme-Catalyzed Cyclization of Geranyl Diphosphate to (4S)-Limonene.
First published: 23 June 2010
Abstract
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ChemInform Abstract
Cyclization of the title diphosphate, catalyzed by a recombinant form of (4S)-limonene synthase, is terminated predominantly by re-facial, anti proton elimination at the cis methyl group, producing (4S)-limonene.
