Volume 29, Issue 11
Isocyclic Compounds
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ChemInform Abstract: Cycloaddition Reactions of 3-Ethoxycarbonyl-2H-cyclohepta[b]furan-2-one with 6,6-Dialkyl, Cycloalkyl, and Diaryl Pentafulvenes.

V. NAIR

V. NAIR

Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India

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G. ANILKUMAR

G. ANILKUMAR

Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India

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K. V. RADHAKRISHNAN

K. V. RADHAKRISHNAN

Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India

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M. V. NANDAKUMAR

M. V. NANDAKUMAR

Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India

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S. KUMAR

S. KUMAR

Org. Chem. Div., Reg. Res. Lab., CSIR, Trivandrum 695 019, Kerala, India

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First published: 23 June 2010

Abstract

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ChemInform Abstract

Competing [8 + 2] and [4 + 2] modes of addition are observed in the title reactions. MNDO and AM1 calculations are carried out to explain the results.

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