Volume 29, Issue 11
Preparative Organic Chemistry
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ChemInform Abstract: Platinum-Catalyzed Regioselective Silaboration of Alkenes.

M. SUGINOME

M. SUGINOME

Dep. Synth. Chem. Biol. Chem., Fac. Eng., Kyoto Univ., Sakyo, Kyoto 606-01, Japan

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H. NAKAMURA

H. NAKAMURA

Dep. Synth. Chem. Biol. Chem., Fac. Eng., Kyoto Univ., Sakyo, Kyoto 606-01, Japan

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Y. ITO

Y. ITO

Dep. Synth. Chem. Biol. Chem., Fac. Eng., Kyoto Univ., Sakyo, Kyoto 606-01, Japan

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First published: 23 June 2010

Abstract

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ChemInform Abstract

In the presence of a platinum—phosphine catalyst, the addition of the B—Si bond to the C—C double bond of alkenes takes place with regioselective bond formation between silicon and the terminal C-atom.

chemical structure image

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