Preparative Organic Chemistry
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ChemInform Abstract: Rhenium-Catalyzed Oxidation of Thiols and Disulfides with Sulfoxides.
First published: 24 June 2010
Abstract
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ChemInform Abstract
The catalytic Re—Me2SO system oxidizes thiols and dithiols to disulfides under very mild conditions. Changing the sulfoxide component of the catalytic system from Me2SO to Ph2SO results in rapid oxidation of the disulfides.
