Volume 29, Issue 1
Preparative Organic Chemistry
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ChemInform Abstract: Epoxidation and Hydroxylation Reactions Catalyzed by β-Tetrahalogeno and β-Octahalogeno Manganese Porphyrins.

E. BACIOCCHI

E. BACIOCCHI

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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T. BOSCHI

T. BOSCHI

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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L. CASSIOLI

L. CASSIOLI

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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C. GALLI

C. GALLI

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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A. LAPI

A. LAPI

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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P. TAGLIATESTA

P. TAGLIATESTA

Dip. Chim., Univ. La Sapienza, CNR, I-00185 Roma, Italy

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First published: 24 June 2010

Abstract

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ChemInform Abstract

With H2O2 as oxygen donor, Mn(III) tetra-β-halogeno porphyrin (Ib) is found to be more efficient catalysts than the corresponding octahalogenated analogues, both in the hydroxylation of adamantane and in the epoxidation of cyclooctene.

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