ChemInform Abstract: Epoxidation and Hydroxylation Reactions Catalyzed by β-Tetrahalogeno and β-Octahalogeno Manganese Porphyrins.
Abstract
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ChemInform Abstract
With H2O2 as oxygen donor, Mn(III) tetra-β-halogeno porphyrin (Ib) is found to be more efficient catalysts than the corresponding octahalogenated analogues, both in the hydroxylation of adamantane and in the epoxidation of cyclooctene.