Volume 29, Issue 1
Preparative Organic Chemistry
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ChemInform Abstract: Water-Soluble Calixarenes as New Inverse Phase-Transfer Catalysts. Nucleophilic Substitution of Alkyl and Arylalkyl Halides in Aqueous Media.

S. SHIMIZU

S. SHIMIZU

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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K. KITO

K. KITO

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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Y. SASAKI

Y. SASAKI

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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C. HIRAI

C. HIRAI

Dep. Ind. Chem., Coll. Ind. Technol., Nihon Univ., Narashino, Chiba 275, Japan

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First published: 24 June 2010

Abstract

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ChemInform Abstract

The substitution of halides like (I) with nucleophiles such as (II) is found to be catalyzed by water-soluble calixarenes, e.g. OSC. The tested calixarenes are more efficient than, for instance, β-cyclodextrin.

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