ChemInform Abstract: Studies in Sigmatropic Rearrangement of 3-(4-Aryloxybut-2-ynyloxy)-1- methylquinolin-2-ones: Synthesis of 3H-Pyrano(2,3-c)quinolin-5(6H)- ones and Furo(2,3-c)quinolin-4(5H)-ones.
Abstract
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ChemInform Abstract
An efficient new method for the selective synthesis of the title compounds (IV) and (V) is presented. AIBN, hydroquinone or a base like dimethylaniline have no effect on the formation of the products. It is noteworthy that (IVd) is not obtained under different conditions.