Volume 28, Issue 50
Heterocyclic Compounds
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ChemInform Abstract: The Preparations and Some Properties of Mixed Aryl-Thienyl Oligomers and Polymers.

A. PELTER

A. PELTER

Dep. Chem., Univ. Wales, Singleton Park, Swansea SA2 8PP, UK

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I. JENKINS

I. JENKINS

Dep. Chem., Univ. Wales, Singleton Park, Swansea SA2 8PP, UK

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D. E. JONES

D. E. JONES

Dep. Chem., Univ. Wales, Singleton Park, Swansea SA2 8PP, UK

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First published: 02 August 2010

Abstract

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ChemInform Abstract

A large number of oligomers such as (III), (VI), (IX), and (X) as well as polymers are prepared by transition metal-catalyzed coupling reactions including a new method using arylcadmium chlorides as substrates. The polymers have metal-like properties and their p-type doping with I2 or FeCl3 leads to large enhancements in conductivity.

chemical structure image

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