Isocyclic Compounds
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ChemInform Abstract: Photochemical Reactions of Oligosilanes with C60.
First published: 02 August 2010
Abstract
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ChemInform Abstract
tBu-substituted disilanes of type (II) react with C60 on irradiation to give 1,16-adducts of type (III). In the case of the Tms-substituted analogue (IV) the 1,2-adduct (VI) is obtained as well. This type of adduct is exclusively formed in the case of phenylsilanes (V) via silyl migration.
