Volume 28, Issue 20
Preparative Organic Chemistry
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ChemInform Abstract: Asymmetric Allylic Alkylation Catalyzed by Palladium Complexes with a New Chiral Bisphosphine Ligand.

J. M. LONGMIRE

J. M. LONGMIRE

Dep. Chem., Pa. State Univ., University Park, PA 16802, USA

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G. ZHU

G. ZHU

Dep. Chem., Pa. State Univ., University Park, PA 16802, USA

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X. ZHANG

X. ZHANG

Dep. Chem., Pa. State Univ., University Park, PA 16802, USA

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First published: 04 August 2010

Abstract

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ChemInform Abstract

A novel chiral bisphosphine ligand (99% e.e.) shows high reactivity, but moderate selectivity in the title alkylation.

chemical structure image

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