Volume 28, Issue 19
Natural Products
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ChemInform Abstract: A Unified Total Synthesis of the Immunomodulators (-)-Rapamycin and (-) -27-Demethoxyrapamycin: Construction of the C(21-42) Perimeters.

A. B. III SMITH

A. B. III SMITH

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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S. M. CONDON

S. M. CONDON

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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J. A. MCCAULEY

J. A. MCCAULEY

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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J. L. JUN. LEAZER

J. L. JUN. LEAZER

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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J. W. LEAHY

J. W. LEAHY

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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R. E. JUN. MALECZKA

R. E. JUN. MALECZKA

Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA

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First published: 04 August 2010

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform Abstract

With regard to the total synthesis of the title antibiotics, the building blocks (I)-(III) are prepared and coupled to the northern C( 21-42) segment of the compounds.

chemical structure image

    The full text of this article hosted at iucr.org is unavailable due to technical difficulties.