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ChemInform Abstract: Carbonyl-Ene Approach to the Asymmetric Synthesis of 2-Keto-3-deoxy-D- gluconic Acid (KDG): A Combinatorial Sequence Using Sharpless Epoxidation.
First published: 04 August 2010
Abstract
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ChemInform Abstract
The asym. approach to title acid (VIII) (in equilibrium with its furanose form) is based on the highly E-selective glyoxylate-ene reaction of the homoallyl silyl ether (I) and the asym. Sharpless epoxidation of the (E)-allylic alcohol (VI).
