Preparative Organic Chemistry
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ChemInform Abstract: Synthesis of Di(2-bromoalkyl) Disulfides Based on the Electrophilic Addition of Dithiobisamines to Olefins.
First published: 04 August 2010
Abstract
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ChemInform Abstract
A new method for the synthesis of di(2-haloalkyl) disulfides by phosphorus halides or oxohalides promoted reaction of dithiobisamines with olefins is accomplished. Reaction of norbornadiene (IV) under the above conditions provides the expected disulfides (cf. (V)/(VI)) or the thiatricyclononane (VII) depending on the reactant ratio.
