Volume 28, Issue 13
Preparative Organic Chemistry
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ChemInform Abstract: Selective Reduction of Carbonyl Compounds with B- Alkoxydiisopinocampheylborane.

J. S. CHA

J. S. CHA

Dep. Chem., Yeungnam Univ., Kyongsan 712-749, S. Korea

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O. O. KWON

O. O. KWON

Dep. Chem., Yeungnam Univ., Kyongsan 712-749, S. Korea

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J. M. KIM

J. M. KIM

Dep. Chem., Yeungnam Univ., Kyongsan 712-749, S. Korea

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First published: 04 August 2010

Abstract

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ChemInform Abstract

Especially aldehydes and α,β-unsaturated aldehydes, e.g. ( Ia)-(Id), are reduced effectively under mild conditions using the title boranes, e.g. Ipc2BOtBu. Hexanal (Ia) is reduced selectively in the presence of acid chlorides, esters and ketones.

chemical structure image

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