Preparative Organic Chemistry
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ChemInform Abstract: Selective Cleavage of Carboxylic Esters in the Presence of Monosubstituted Malonates.
First published: 25 August 2010
Abstract
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ChemInform Abstract
Aliphatic carboxylic esters containing a malonate moiety with a α -hydrogen undergo highly selective cleavage by treatment with wet tBuOK in THF (cf. (II), (IV), (VI)).
