Preparative Organic Chemistry
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ChemInform Abstract: Syntheses of (-)-Isocitric Acid Lactone and (-)-Homoisocitric Acid. A New Method of Conversion of Alkynylsilanes into the Alkynyl Thioether and Corresponding Carboxylic Acids.
First published: July 16, 1996
Abstract
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ChemInform Abstract
The title compounds (VIII) and (XII) are stereoselectively synthesized. The synthesis of (XII) is based on a new method for the conversion of the alkynyl thioether (XI) to the carboxylic acid (XII) of the same chain length. This novel method is applied to silanes (XIII).
