ChemInform Abstract: Scope and Limitation of the (1,4) SPh Shift in the Synthesis of Allylic Alcohols.
Abstract
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ChemInform Abstract
The rearrangement of 4-phenylthio substituted alcohols with tosyl chloride in pyridine results in general in formation of alkenes such as (II), (IV), or (VIII). However, some limitations of the reaction due to structural variations of the educts, e.g. (V), are also reported.