Organoelement Compounds
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ChemInform Abstract: Polylithiumorganic Compounds. Part 22. Synthesis of the First Titana(3) radialene and Its Ring Enlargement to a Titanacyclopentene.
First published: April 30, 1996
Abstract
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ChemInform Abstract
The initial product of the reaction of (I) with (II), i.e. the radialene (III), is not isolable, but rearranges immediately to (IV). The structures of both compounds are determined unequivocally by their NMR data and data for derivatives of (IV) such as (VI).
