ChemInform Abstract: Studies on the Transannular Diels-Alder Reaction of 15-Membered Macrocyclic Trienes Containing a trans-trans Diene. Part 1. Synthesis and Isomerization of Various Model Cyclopentadecatrienes.
Abstract
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ChemInform Abstract
Ten model cyclopentadecatrienes of the types (I) and (II) are prepared from functionalized trisubstituted dienophile and diene synthons in order to study the influence of the position and the nature of the dienophile substituents on the tricyclic products of their transannular Diels-Alder reaction.