Volume 27, Issue 18
Preparative Organic Chemistry
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ChemInform Abstract: Annulated Ring-Systems by Domino-Heck-Aldol-Condensation and Domino- Heck-Michael-Addition Processes.

G. DYKER

G. DYKER

Org./Organomet. Chem., Gerhard-Mercator-Univ.-GH, D-47048 Duisburg, Germany

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P. GRUNDT

P. GRUNDT

Org./Organomet. Chem., Gerhard-Mercator-Univ.-GH, D-47048 Duisburg, Germany

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First published: April 30, 1996

Abstract

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ChemInform Abstract

The Pd-catalyzed coupling reaction of appropriately functionalized aryl bromides (I) and (VI) with allylic alcohols (II) and (VII) results in 5-membered ring annulation, whereas with homoallylic alcohols, e.g. (IV) 6-membered rings are formed.

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