ChemInform Abstract: Transglycosylation Reactions of Permethylated Methyl D- Glucopyranosides with Partially Methylated 1,5-Anhydroalditols.
Abstract
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ChemInform Abstract
Transglycosylation of permethylated methyl D-glucopyranosides (cf. (I)) with 1,5-anhydro-D-glucitols under conditions of reductive oligosaccharide cleavage provides disaccharide derivatives as mixtures of anomers. A disaccharide which could be formed by a transglycosylation reaction is observed during the reductive cleavage of permethylated pullulan.