ChemInform Abstract: Synthesis of a Novel Cyclic Germanium Enamine from Germylene and 2- Vinylpyridine and Its Stereoselective Aldol Type Reaction with Aldehydes.
Abstract
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ChemInform Abstract
Stereoselective reaction of cyclic Ge(IV)-enamine (III) resulting from oxidative addition of vinylpyridine (I) to Ge(II)-compound (II), with aliphatic aldehydes yields predominantly trans diastereomers (VI). With aromatic aldehydes mainly cis diastereomers (V) are obtained.