Volume 27, Issue 16
Organoelement Compounds
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ChemInform Abstract: Synthesis of a Novel Cyclic Germanium Enamine from Germylene and 2- Vinylpyridine and Its Stereoselective Aldol Type Reaction with Aldehydes.

S. IWATA

S. IWATA

Dep. Mol. Chem. Eng., Fac. Eng., Tohoku Univ., Aoba, Sendai 980, Japan

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S. SHODA

S. SHODA

Dep. Mol. Chem. Eng., Fac. Eng., Tohoku Univ., Aoba, Sendai 980, Japan

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S. KOBAYASHI

S. KOBAYASHI

Dep. Mol. Chem. Eng., Fac. Eng., Tohoku Univ., Aoba, Sendai 980, Japan

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First published: April 16, 1996

Abstract

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ChemInform Abstract

Stereoselective reaction of cyclic Ge(IV)-enamine (III) resulting from oxidative addition of vinylpyridine (I) to Ge(II)-compound (II), with aliphatic aldehydes yields predominantly trans diastereomers (VI). With aromatic aldehydes mainly cis diastereomers (V) are obtained.

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