Preparative Organic Chemistry
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ChemInform Abstract: Diastereoselective Reduction of α-(p-Tolylsulfinyl)ketoximes.
First published: April 16, 1996
Abstract
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ChemInform Abstract
Treatment of α-sulfinylketoximes according to A) results in the first reported diastereoselective reduction via a nonchelate model yielding (S)-(N-methoxyamino)sulfoxides. Further reductive fission of the C-S and N-O bonds of the products, e.g. (IIc) followed by acetylation leads to chiral amines (V), thus providing a suitable approach to this type of compounds.
