Volume 27, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Active Metal Tin Promoted Allylation of Imidazoles and Its Derivatives via Unstable N-(Alkoxycarbonyl)azolium Salts.

J.-Y. ZHOU

J.-Y. ZHOU

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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Z.-G. CHEN

Z.-G. CHEN

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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S.-H. WU

S.-H. WU

Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China

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First published: April 16, 1996

Abstract

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ChemInform Abstract

Imidazoles (I) or the thiazole (V) undergo a tin-mediated reaction with allylic bromides in the presence of chloroformates to form the corresponding 2-allylated heterocycles.

chemical structure image

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