Volume 27, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Enantioselective Allylic Oxidation Using Biomimetic Tris(oxazolines)- Copper(II) Complex.

K. KAWASAKI

K. KAWASAKI

Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812-81, Japan

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S. TSUMURA

S. TSUMURA

Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812-81, Japan

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T. KATSUKI

T. KATSUKI

Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812-81, Japan

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First published: April 16, 1996

Abstract

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ChemInform Abstract

The chiral ligand TOA is used as catalyst together with Cu(O-Tf)2 in the asymmetric allylic oxidation of the simple cycloalkenes (I). Such a type of ligands is a model compound of the active site of non-heme oxygenase.

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