ChemInform Abstract: Enantioselective Allylic Oxidation Using Biomimetic Tris(oxazolines)- Copper(II) Complex.
Abstract
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ChemInform Abstract
The chiral ligand TOA is used as catalyst together with Cu(O-Tf)2 in the asymmetric allylic oxidation of the simple cycloalkenes (I). Such a type of ligands is a model compound of the active site of non-heme oxygenase.