Heterocyclic Compounds
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ChemInform Abstract: Highly Enantioselective Route to β-Lactams via Intramolecular C-H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates.
First published: March 12, 1996
Abstract
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ChemInform Abstract
The carbenes obtained by decomposition of the diazoacetylazacycloalkanes (I), (III), and (VI) undergo highly enantioselective intramolecular C-H insertion reactions under conditions A) to form the corresponding β- and γ-lactams.
