Volume 27, Issue 11
Heterocyclic Compounds
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ChemInform Abstract: Stereochemical Investigation of Aldol Condensations Using (3R)- and ( 3S)-3-Benzylpiperazine-2,5-dione Derivatives.

M. C. D'ARRIGO

M. C. D'ARRIGO

Dip. Chim. “G. Ciamician”, Univ. Studi Bologna, I-40126 Bologna, Italy

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G. PORZI

G. PORZI

Dip. Chim. “G. Ciamician”, Univ. Studi Bologna, I-40126 Bologna, Italy

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S. SANDRI

S. SANDRI

Dip. Chim. “G. Ciamician”, Univ. Studi Bologna, I-40126 Bologna, Italy

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First published: March 12, 1996

Abstract

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ChemInform Abstract

The title investigation is carried out in order to study the influence of epimerization at the C-3 position of piperazine-2,5-dione (I) on the asymmetric induction in aldol additions at the C-6 position. The configuration of the new stereocenters are assigned by spectroscopical means and conformational analysis.

chemical structure image

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