ChemInform Abstract: Synthesis and Oxidation of the Decarbonylated Adducts Generated from Alkenes and Tricarbonyl(vinylketene)iron(0) Complexes.
Abstract
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ChemInform Abstract
(Vinylketene)iron complexes such as (I) react with electron-deficient alkenes to give the decarbonylated adducts (III) and (VI) which under oxidative conditions give a variety of organic products such as cyclopropanes, lactones or cyclobutanes. An X-ray crystal structure analysis of the adduct (III) and a mechanistic explanation for the formation of the adducts are presented.
