ChemInform Abstract: Synthesis of Pisiferol Revisited; Control of Stereochemistry in an Intramolecular Diels-Alder Reaction.
Abstract
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ChemInform Abstract
The presence of a PhSO2 group in compound (III) favors the formation of trans-product (IV) versus cis-product (V) upon thermolysis. (IV) is an interesting precursor for the synthesis of pisiferol (VII).