Volume 26, Issue 19
Natural Products
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ChemInform Abstract: Synthesis of Pisiferol Revisited; Control of Stereochemistry in an Intramolecular Diels-Alder Reaction.

E. J. BUSH

E. J. BUSH

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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D. W. JONES

D. W. JONES

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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M. THORNTON-PETT

M. THORNTON-PETT

Sch. Chem., Univ. Leeds, Leeds LS2 9JT, UK

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First published: May 9, 1995

Abstract

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ChemInform Abstract

The presence of a PhSO2 group in compound (III) favors the formation of trans-product (IV) versus cis-product (V) upon thermolysis. (IV) is an interesting precursor for the synthesis of pisiferol (VII).

chemical structure image

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