Physical Organic Chemistry
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ChemInform Abstract: cis- and trans-Configurations of α,α′-Disubstituted Piperidines and Pyrrolidines by GC-FTIR; Application to Decahydroquinoline Stereochemistry.
First published: March 14, 1995
Abstract
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ChemInform Abstract
GC-FTIR spectroscopy proves to be a simple and rapid method for the determination of the relative configuration of cis- and trans-2,6- disubstituted piperidines and 2,5-disubstituted pyrrolidines when present in very small amounts. This method is also applicable to complex mixtures such as extracts of alkaloids with piperidine or hydroquinoline moieties.
