Organoelement Compounds
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ChemInform Abstract: Synthesis of Allylsilanes by Palladium(0) Catalyzed Reduction of Trialkylsilylallyl Esters.
First published: February 28, 1995
Abstract
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ChemInform Abstract
Conversion of the vinylsilane (I) to a Pd(O) complex followed by reduction using sodium formate or butylzinc chloride yields the allylsilane (II) as the major product. When (IV) is treated similarly, the diene (VII) is formed with predominance. The tosylate (VIII) is selctively reduced to give the allylidenecyclopropane (IX) or the vinylcyclopropane (X).
